Back Cover: Site‐Specific Reduction‐Induced Hydrogenation of a Helical Bilayer Nanographene with K and Rb Metals: Electron Multiaddition and Selective Rb <sup>+</sup> Complexation (Angew. Chem. Int. Ed. 10/2022)

نویسندگان

چکیده

Reduction-induced hydrogenation of a helical bilayer nanographene (C138H120) with K or Rb in 18-crown-6 is reported by Israel Fernández, Marina A. Petrukhina, Nazario Martín, and co-workers their Research Article (e202115747). DFT calculations predict that localization the first two electrons helicene moiety leads to site-specific at carbon atoms located on edge central [6]helicene backbone (pink hydrogens). The third electron forms radical trianion HBC leading final complex.

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2022

ISSN: ['1521-3773', '1433-7851', '0570-0833']

DOI: https://doi.org/10.1002/anie.202201129